{"id":3801,"date":"2024-05-01T17:26:25","date_gmt":"2024-05-01T09:26:25","guid":{"rendered":"\/chemistry\/?p=3801"},"modified":"2024-09-13T09:55:54","modified_gmt":"2024-09-13T01:55:54","slug":"%e8%ac%9d%e5%bf%a0%e5%ae%8f","status":"publish","type":"post","link":"\/chemistry\/?p=3801","title":{"rendered":"\u8b1d\u5fe0\u5b8f(\u671f\u520a)"},"content":{"rendered":"\n<div class=\"wp-block-tkuwpbs5-bs5-container container chem_teach\" style=\"margin-top:var(--wp--preset--spacing--40);padding-top:var(--wp--preset--spacing--50);padding-bottom:var(--wp--preset--spacing--50);position:relative\" block_id=\"lq3fs6oyzthhmnpj8a\"><style><\/style>\n<div class=\"wp-block-tkuwpbs5-bs5-row row\">\n<h4 class=\"wp-block-heading\"><strong>\u767c\u8868\u8ad6\u6587<\/strong><\/h4>\n\n\n\n<p>1. A Reduced 2Fe2S Cluster Probe of Sulfur-Hydrogen vs. Sulfur-Gold Interactions. Crouthers, D. J.; Ding, S.; Denny, J. A.; Bethel, R. D.;&nbsp;<strong>Hsieh, C.-H.<\/strong>; Hall, M. B.; Darensbourg, M. Y.,&nbsp;<em><u>Angew. Chemie, Int. Ed.,<\/u><\/em><strong><u>2015<\/u><\/strong>,54,Accepted manuscript.<\/p>\n\n\n\n<p>2. Regioselectivity in Ligand Substitution Reactions on Diiron Complexes Governed by Nucleophilic and Electrophilic Ligand Properties. Bethel, R. D.; Crouthers, D. J.;&nbsp;<strong>Hsieh, C.-H.<\/strong>; Denny, J. A.; Hall, M. B.; Darensbourg, M. Y.,&nbsp;<em><u>Inorg. Chem.<\/u><\/em><strong><u>2015<\/u><\/strong>,54,3523-3535.<\/p>\n\n\n\n<p>2. Metallodithiolates as Ligands to Dinitrosyl Iron Complexes: Toward the Understanding of Structures, Equilibria, and Spin Coupling. Pinder, T. A.; Montalvo, S. K.;&nbsp;<strong>Hsieh, C.-H.<\/strong>; Lunsford, A. M.; Bethel, R. D.; Pierce, B. S.; Darensbourg, M. Y.,&nbsp;<em><u>Inorg. Chem.,<\/u><\/em><strong><u>2014<\/u><\/strong>,53.9095\u20149105.<\/p>\n\n\n\n<p>4. Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes. Pulukkody, R.; Kyran, S. J.; Drummond, M. J.;&nbsp;<strong>Hsieh, C.-H.<\/strong>; Darensbourg, D. J.; Darensbourg, M. Y.,&nbsp;<em><u>Chem.Sci.<\/u><\/em>,<strong>2014<\/strong>,5,3795\u20143802.&nbsp;<\/p>\n\n\n\n<p>5. Redox active iron nitrosyl units in proton reduction electrocatalysis. <strong>Hsieh, C.-H<\/strong>.; Ding, S.; Erdem, \u00d6. F.; Crouthers, D. J.; Lubitz, W.; Popescu, C. V.; Reibenspies, J. H.; Hall, M. B.; Darensbourg, M. Y., <em><u>Nature Communications,<\/u><\/em><strong><u>2014<\/u><\/strong>,5,Article number 3684.<\/p>\n\n\n\n<p>6. A Dinitrosyl Iron Complex as a Platform for Metal-Bound Imidazole to N-Heterocyclic Carbene Conversion.Randara Pulukkody, Samuel J. Kyran , Ryan D. Bethel ,&nbsp;<strong>Chung-Hung Hsieh<\/strong>&nbsp;, Michael B. Hall , Donald J. Darensbourg, Marcetta Y. Darensbourg,&nbsp;<em>&nbsp;<u>Chem. Comm.<\/u><\/em>&nbsp;<strong>2013<\/strong>,&nbsp;49, 9326-9328.<\/p>\n\n\n\n<p>7. Versatile N2S2 Nickel-dithiolates as Mono- and Bridging Bidentate, S-donor Ligands to Gold(I). Pinder T. A.; Montalvo, S. K.; Lunsford, A. M.;&nbsp;<strong>Hsieh,C.-H.<\/strong>;&nbsp;Reibenspies,J. H.; Darensbourg, M. Y.*, <em><u>Dalton Trans<\/u><\/em>.,&nbsp;<strong>2013<\/strong>,&nbsp;43, 138-144.&nbsp;<\/p>\n\n\n\n<p>8. Carbon Monoxide Induced Reductive Elimination of Disulfide in an N-Heterocyclic Carbene (NHC)\/ Thiolate Dinitrosyl Iron Complex (DNIC). Randara Pulukkody, Samuel J. Kyran, Ryan D. Bethel,&nbsp;<strong>Chung-Hung Hsieh<\/strong>, Michael B. Hall, Donald J. Darensbourg, Marcetta Y. Darensbourg, <em><u>J. Am. Chem. Soc.<\/u><\/em>,&nbsp;<strong>2013<\/strong>,&nbsp;135, 8423-8430.&nbsp;<\/p>\n\n\n\n<p>9. Ambidentate Thiocyanate and Cyanate Ligands in Dinitrosyl Iron Complexes. <strong>Chung-Hung Hsieh<\/strong>, Scott M. Brothers, Joseph H. Reibenspies, Michael B. Hall, Codrina V. Popescu, Marcetta Y. Darensbourg, <em><u>Inorg. Chem<\/u><\/em>.&nbsp;<strong>2013<\/strong>, 52, 2119-2124.<\/p>\n\n\n\n<p>10. Bridging-Hydride Influence on the Electronic Structure of an [FeFe]-Hydrogenase Active-Site Model Complex Revealed by XAES-DFT. N. Leidel,&nbsp;<strong>C-H Hsieh<\/strong>, P. Chernev, K. G. V. Sigfridsson, M. Y. Darensbourg, M. Haumann, <em><u>Dalton&nbsp;Trans.<\/u><\/em>,&nbsp;<strong>2013<\/strong><em>,<\/em>&nbsp;42, 7539-7554.&nbsp;<\/p>\n\n\n\n<p>11. Hyperfine interactions and electron distribution in Fe(II)Fe(I) and Fe (I)Fe (I) models for the active site of the [FeFe] hydrogenases: Mossbauer spectroscopy studies of low-spin Fe(I). Sebastian A. Stoian,<strong>&nbsp;Chung-Hung Hsieh<\/strong>, Michael L. Singleton, Andrea F. Casuras, Marcetta Y. Darensbourg, Kelsey McNeely, Kurt Sweely, Codrina V. Popescu, <em><u>J. Bio. Inorg. Chem.<\/u><\/em>,&nbsp;<strong>2013<\/strong>, 18, 609-622.<\/p>\n\n\n\n<p>12. Structural and Spectroscopic Features of Mixed Valent FeIIFeI Complexes and Factors Related to the Rotated Configuration of Diiron Hydrogenase. <strong>Hsieh, C.-H.<\/strong>; Erdem, \u00d6. F.; Harman, S. D.; Singleton, M. L.; Reijerse, E.; Lubitz, W.; Popescu, C. V.; Reibenspies, J. H.; Brothers, S. M.; Hall, M. B.; Darensbourg, M. Y.,&nbsp;<em><u>J. Am. <\/u><\/em><em><u>Chem. Soc<\/u><\/em>.&nbsp;<strong>2012<\/strong>,134, 13089\u201313102.<\/p>\n\n\n\n<p>13. Dinitrosyl Iron Adducts of (N<sub>2<\/sub>S<sub>2<\/sub>)M(NO) Complexes (M = Fe, Co) as Metallodithiolate Ligands. <strong>Chung-Hung Hsieh<\/strong>, Rachel B. Chupik, Tiffany A. Pinder, Marcetta Y. Darensbourg, <em><u>Polyhydron<\/u><\/em>,&nbsp;<strong>2013<\/strong>, 58, 151-155.<\/p>\n\n\n\n<p>14. Towards Understanding the Electronic Response of the Fe(NO)<sub>2<\/sub>&nbsp;Unit to \u201cSpectator\u201d Ligands in Dinitrosyl Iron Complexes. Brothers, S. M.; Hess, J. L.;<strong>&nbsp;Hsieh, C.-H.<\/strong>;&nbsp;Darensbourg, M. Y.*; Hall, M. B.*, <em><u>Structure and Bonding<\/u><\/em>,&nbsp;<strong>2012<\/strong>, submitted.&nbsp;<\/p>\n\n\n\n<p>15. Self-Assembly of Dinitrosyl Iron Units into Imidazolate-Edge-Bridged Molecular Squares: Characterization Including Mossbauer Spectroscopy. J. L Hess,&nbsp;<strong>C.-H. Hsieh<\/strong>, S. M. Brothers, M. B. Hall, M. Y. Darensbourg, <em><u>J. Am. Chem. Soc.&nbsp;<\/u><\/em><strong><u>2011<\/u><\/strong>, 133, 20426\u201320434.&nbsp;<\/p>\n\n\n\n<p>16. N-Heterocyclic carbene ligands as mimics of histidines for the stabilization of di- and tri-nitrosyl iron complexes. Jennifer L. Hess,&nbsp;<strong>Chung-Hung Hsieh<\/strong>, Joseph H. Reibenspies, M. Y. Darensbourg, <em><u>Inorg. Chem.&nbsp;<\/u><\/em><strong><u>2011<\/u><\/strong>, 50, 8541-8552.&nbsp;&nbsp;<\/p>\n\n\n\n<p>17. cis-Dithiolatonickel as Metalloligand to Dinitrosyl Iron Units: the Di-Metallic Structure of Ni(\u03bc-SR)[Fe(NO)2] and an Unexpected, Abbreviated Metalloadamantyl Cluster, Ni2(\u03bc-SR)4[Fe(NO)2]3.&nbsp;<strong>Chung-Hung Hsieh<\/strong>, Rachel B. Chupik, Scott M. Brothers, Michael B. Hall, Marcetta Y. Darensbourg, <em><u>Dalton Trans.&nbsp;<\/u><\/em><strong><u>2011<\/u><\/strong>, 40, 6047-6053.&nbsp;<\/p>\n\n\n\n<p>18. A {Fe(NO)3}10&nbsp;Trinitrosyliron Complex Stabilized by an N-Heterocyclic Carbene and the Cationic and Neutral {Fe(NO)2}9\/10&nbsp;Products of Its NO Release. <strong>Chung-Hung Hsieh<\/strong>, Marcetta Y. Darensbourg, <em><u>J. Am. Chem. Soc.,<\/u><\/em><strong><u>2010<\/u><\/strong>,132, 14118\u201314125.&nbsp;<\/p>\n\n\n\n<p>19. Nitric Oxide Physiological Responses and Delivery Mechanisms Probed by Water-soluble Roussin\u2019s Red Ester and {Fe(NO)<sub>2<\/sub>}<sup>10<\/sup>&nbsp;DNIC. Chen, Y.-J.; Ku, W.-C.; Feng, L.-T.; Tsai, M.-L.;&nbsp;<strong>Hsieh, C.-H.<\/strong>;&nbsp;Hsu, W.-H.; Liaw, W.-F.*; Hung, C.-H.*; Chen, Y.-J.*, <em><u>J. Am. <\/u><\/em><em><u>Chem. Soc<\/u><\/em>.&nbsp;<strong>2008<\/strong>, 130, 10929-10938.<\/p>\n\n\n\n<p>20. Dinitrosyl Iron Complexes (DNICs) Containing S\/N\/O Ligation: Transformation of Roussin\u2019s Red Ester into the Neutral {Fe(NO)} DNICs. Tsai, M.-L.;&nbsp;<strong>Hsieh, C.-H.;<\/strong>&nbsp;Liaw, W.-F.*, <em><u>Inorg. Chem.<\/u><\/em>,&nbsp;<strong>2007<\/strong>;&nbsp;<em>46<\/em>, 5110-5117&nbsp;<\/p>\n\n\n\n<p>21. New members of a Class of Iron-Thiolate-Nitrosyl Compounds: Trinuclear Iron-Thiolate-Nitrosyl Complexes Containing FeS Core. Hsu, I.-J.;<strong>&nbsp;Hsieh C.-H.<\/strong>;&nbsp;Ke S.-C.*; Chiang K.-A.; Lee J.-M.; Chen J.-M.; Jang L.-Y.; Lee G.-H.; Wang Y.*; Liaw, W.-F.*, <em><u>J. Am. <\/u><\/em><em><u>Chem. Soc.<\/u><\/em>&nbsp;<strong>2007<\/strong>,&nbsp;<em>129<\/em>, 1151-1159<\/p>\n\n\n\n<p>22. Photochemistry of the Dinitrosyl Iron Complex [S<sub>5<\/sub>Fe(NO)<sub>2<\/sub>]<sup>&#8211;<\/sup>&nbsp;Leading to Reversible Formation of [S<sub>5<\/sub>Fe(\u03bc-S)<sub>2<\/sub>FeS<sub>5<\/sub>]<sup>2-<\/sup>: Spectroscopic Characterization of Species Relevant to the Nitric Oxide Modification and Repair of [2Fe-2S] Ferredoxin. Tsai, M.-L.; Chen, C.-C.; Hsu, I.-J.; Ke, S.-C.;&nbsp;<strong>Hsieh, C.-H.<\/strong>;&nbsp;Chiang, K.-A.; Lee, G.-H.; Wang, Y.; Chen, J.-M.; Lee, J.-F.; Liaw, W.-F. *, <em><u>Inorg.&nbsp;Chem.<\/u><\/em>,&nbsp;<strong>2004<\/strong>;&nbsp;<em>43<\/em>, 5159-5167&nbsp;<\/p>\n\n\n\n<p>23. Oxygen Binding to Sulfur in Nitrosylated Iron-Thiolate Complexes: Relevance to the Fe-Containing Nitrile Hydratases. Lee,C.-M.;&nbsp;<strong>Hsieh, C.-H.<\/strong>;&nbsp;Dutta, A.; Lee, G.-H.; Liaw, W.-F.*, <em><u>J. Am. Chem. Soc.<\/u><\/em>&nbsp;<strong>2003<\/strong>,&nbsp;<em>125<\/em>, 11492-11493&nbsp;<\/p>\n\n\n\n<p>24. Nickel Complex of&nbsp;<em>o<\/em>-amidochalcogenophenolate (2-) \/<em>o<\/em>-iminochalcogenobenzosemiquinonate (1-) \u03c0-radical: Synthesis, Structures, Electron Spin Resonance and X-ray Absorption Spectroscopic Evidence. <strong>Hsieh, C.-H.<\/strong>;&nbsp;Hsu, I-J.; Lee, C.-M.; Ke S.-C.; Wang T.-Y.; Lee G.-Hs.; Wang, Y.; Chen, J.-M.; Lee, J.-F.; Liaw, W.-F.*, <em><u>Inorg. Chem.<\/u><\/em>&nbsp;<strong>2003<\/strong>,&nbsp;<em>42<\/em>, 3925-3933.&nbsp;<\/p>\n\n\n\n<p>25. Bioinorganic and Coordinated Chemistry. Chen; C.-H.; Lee, C.-M.;&nbsp;<strong>Hsieh, C.-H.<\/strong>;&nbsp;Liaw, W.-F.*, <em><u>Chemistry<\/u><\/em>&nbsp;(The Chinese Chem. Soc., Taipei)&nbsp;<strong>2003<\/strong>,&nbsp;<em>61<\/em>, 79-86.&nbsp;<\/p>\n\n\n\n<p>26. S-S Bond-activation of diorganyl disulfide by anionic [Mn(CO)<sub>5<\/sub>]<sup>\u2212<\/sup>: crystal structures of [Mn<sup>II<\/sup>(SC<sub>5<\/sub>H<sub>4<\/sub>NO)<sub>3<\/sub>]<sup>\u2212<\/sup>&nbsp;and [(CO)<sub>3<\/sub>Mn(\u03bc-SR)<sub>3<\/sub>Co(\u03bc-SR)<sub>3<\/sub>Mn(CO)<sub>3<\/sub>]<sup>\u2212<\/sup>&nbsp;(R=C<sub>6<\/sub>H<sub>4<\/sub>NHCOPh). Liaw, W.-F.*;&nbsp;<strong>Hsieh, C.-H.<\/strong>;&nbsp;Lee G.-H., <em><u>Inorg. Chim. Acta.<\/u><\/em>&nbsp;<strong>2002<\/strong>,&nbsp;<em>332<\/em>, 153-159&nbsp;<\/p>\n\n\n\n<p>27. Five-Coordinate Sixteen-Elecron Manganese(I) Complex [Mn(CO)<sub>3<\/sub>(S, S-C<sub>6<\/sub>H<sub>4<\/sub>)]<sup>&#8211;<\/sup>&nbsp;Stabilized by S, S \u03c0-Donation of Chelating [S, S-C<sub>6<\/sub>H<sub>4<\/sub>)]<sup>2-<\/sup>&nbsp;Ligand. Lee,C.-M.; Lin, G.-Y.;&nbsp;<strong>Hsieh, C.-H.<\/strong>;&nbsp;Hu, C.-H.; Lee G.-H.; Peng S.-M.; Liaw, W.-F.*, <em><u>J. Chem. Soc., Dalton Trans.<\/u><\/em>&nbsp;<strong>1999<\/strong>, 2393-2398<\/p>\n<\/div>\n\n\n\n<div class=\"wp-block-tkuwpbs5-bs5-row row\">\n<h4 class=\"wp-block-heading\"><strong>\u6f14\u8b1b (2012-&nbsp; )<\/strong><\/h4>\n\n\n\n<p>The 245<sup>th<\/sup>&nbsp;American Chemical Society National Meeting &amp; Exposition,&nbsp;<strong>2013<\/strong><br>Division of Inorganic Chemistry:<br><em>Ambidentate thiocyanate ligand in dinitrosyl iron complexes<\/em><\/p>\n\n\n\n<p>The 244<sup>th<\/sup>&nbsp;American Chemical Society National Meeting &amp; Exposition,&nbsp;<strong>2012<\/strong><br>Division of Inorganic Chemistry:<br><em>Base-Promoted Tautomerization of Imidazoles to N-Heterocyclic Carbenes (NHCs): via a Dinitrosyl Iron scaffold<\/em><\/p>\n<\/div>\n<\/div>\n\n\n\n<div style=\"height:10px\" aria-hidden=\"true\" class=\"wp-block-spacer\"><\/div>\n","protected":false},"excerpt":{"rendered":"","protected":false},"author":26,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"wp-custom-template-member-empty-template","format":"standard","meta":{"footnotes":""},"categories":[1],"tags":[],"acf":[],"_links":{"self":[{"href":"\/chemistry\/index.php?rest_route=\/wp\/v2\/posts\/3801"}],"collection":[{"href":"\/chemistry\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"\/chemistry\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"\/chemistry\/index.php?rest_route=\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"\/chemistry\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=3801"}],"version-history":[{"count":5,"href":"\/chemistry\/index.php?rest_route=\/wp\/v2\/posts\/3801\/revisions"}],"predecessor-version":[{"id":5725,"href":"\/chemistry\/index.php?rest_route=\/wp\/v2\/posts\/3801\/revisions\/5725"}],"wp:attachment":[{"href":"\/chemistry\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=3801"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"\/chemistry\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=3801"},{"taxonomy":"post_tag","embeddable":true,"href":"\/chemistry\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=3801"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}